Learning objectives

Identify the intermolecular forces present in a substance — London dispersion, dipole–dipole, hydrogen bonding and ion–dipole — and rank their relative strengths for given particles

Explain how London dispersion forces arise from instantaneous induced dipoles and why they strengthen with increasing polarisability and molar mass

Explain differences in boiling point, vapor pressure, viscosity, surface tension and enthalpy of vaporization between substances using the intermolecular forces present, not the strength of covalent bonds

Interpret a heating curve and a phase diagram, and explain why temperature stays constant during a phase change while intermolecular forces are overcome

Justify a claim about the relative strength of intermolecular forces in two substances using experimental evidence such as vapor pressure or boiling point data

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